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BPC-157 is a synthetic 15-amino-acid peptide (a pentadecapeptide, sequence Gly-Glu-Pro-Pro-Pro-Gly-Lys-Pro-Ala-Asp-Asp-Ala-Gly-Leu-Val)

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However, the structures of isocereulides E ( 6 ) and F ( 7 ), as well as isocereulide G ( 8 ), which shows another constitutional arrangement of the depsidipeptides D- O -Leu-D-Ala and L- O -Val-L-Val when compared to the isobaric cereulide, violate the canonical NRPS biosynthesis logic as suggested for cereulide production