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10.1016/j.redox.2020.101435 68 KoikeK.YamamotoY.SuzukiN.YamazakiR.YoshikawaC.TakanoF.et al (2013)

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Namely, the long-term storage of peptides at room temperature is generally not recommended, as well as repeated freeze thaw cycles (except of lyophilized peptides)